CobaltMaghrebV1, Main, Exploration, bibRecord, 000207

Tetrakis(μ-2-phenylacetato-κ2O:O′)bis{[4-(dimethylamino)pyridine-κN1]cobalt(II)}

Identifieur interne : 000207 ( Main/Exploration ); précédent : 000206; suivant : 000208

Tetrakis(μ-2-phenylacetato-κ2O:O′)bis{[4-(dimethylamino)pyridine-κN1]cobalt(II)}

Auteurs : Meriem Benslimane [Algérie] ; Yasmine Kheira Redjel [Algérie] ; Georges Dénès [Canada] ; Hocine Merazig [Algérie]

Source :

Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2013.

RBID : PMC:3884428

Abstract

The title compound, [Co₂(C₈H₇O₂)₄(C₇H₁₀N₂)₂], crystallizes as a centrosymmetric dimer containing two Co^II atoms bridged by four bidentate phenylacetate ligands in syn–syn bridging modes. Each Co^II atom is five-coordinated by four O atoms from four different carboxylate ligands and the ring N atom of a 4-(dimethylamino)pyridine unit, generating a distorted square-pyramidal geometry in which the four O atoms form the basal plane and the N atom occupies the axial position. In the crystal, C—H⋯O interactions link the dinuclear complex molecules into a three-dimensional network.

Url:

http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884428

DOI: 10.1107/S1600536813023258
PubMed: 24427006
PubMed Central: 3884428

Affiliations:

Algérie, Canada

Le document en format XML

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<italic>O</italic>
:<italic>O</italic>
′)bis{[4-(dimethylamino)pyridine-κ<italic>N</italic>
<sup>1</sup>
]cobalt(II)}</title>
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<author><name sortKey="Merazig, Hocine" sort="Merazig, Hocine" uniqKey="Merazig H" first="Hocine" last="Merazig">Hocine Merazig</name>
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<italic>O</italic>
:<italic>O</italic>
′)bis{[4-(dimethylamino)pyridine-κ<italic>N</italic>
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<author><name sortKey="Benslimane, Meriem" sort="Benslimane, Meriem" uniqKey="Benslimane M" first="Meriem" last="Benslimane">Meriem Benslimane</name>
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<front><div type="abstract" xml:lang="en"><p>The title compound, [Co<sub>2</sub>
(C<sub>8</sub>
H<sub>7</sub>
O<sub>2</sub>
)<sub>4</sub>
(C<sub>7</sub>
H<sub>10</sub>
N<sub>2</sub>
)<sub>2</sub>
], crystallizes as a centrosymmetric dimer containing two Co<sup>II</sup>
 atoms bridged by four bidentate phenylacetate ligands in <italic>syn–syn</italic>
 bridging modes. Each Co<sup>II</sup>
 atom is five-coordinated by four O atoms from four different carboxylate ligands and the ring N atom of a 4-(dimethylamino)pyridine unit, generating a distorted square-pyramidal geometry in which the four O atoms form the basal plane and the N atom occupies the axial position. In the crystal, C—H⋯O interactions link the dinuclear complex molecules into a three-dimensional network.</p>
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Serveur d'exploration sur le cobalt au Maghreb

Tetrakis(μ-2-phenylacetato-κ2O:O′)bis{[4-(dimethylamino)pyridine-κN1]cobalt(II)}

Tetrakis(μ-2-phenylacetato-κ2O:O′)bis{[4-(dimethylamino)pyridine-κN1]cobalt(II)}

Source :

Abstract

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	Serveur d'exploration sur le cobalt au Maghreb
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Serveur d'exploration sur le cobalt au Maghreb

Tetra­kis(μ-2-phenyl­acetato-κ2O:O′)bis­{[4-(di­methyl­amino)­pyridine-κN1]cobalt(II)}

Tetra­kis(μ-2-phenyl­acetato-κ2O:O′)bis­{[4-(di­methyl­amino)­pyridine-κN1]cobalt(II)}

Source :

Abstract

Links toward previous steps (curation, corpus...)

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Pour manipuler ce document sous Unix (Dilib)

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Tetrakis(μ-2-phenylacetato-κ2O:O′)bis{[4-(dimethylamino)pyridine-κN1]cobalt(II)}

Tetrakis(μ-2-phenylacetato-κ2O:O′)bis{[4-(dimethylamino)pyridine-κN1]cobalt(II)}